1.        1a

2.        Glycolysis vs gluconeogenesis- three irreversible reactions

3.        Use the jumping bean diagrams:
     EQUILIBRIUM CONSTANT- measures number or products versus reactants at equilibrium: Keq =number of beans in chamber 2 / those in chamber 1This is = at equilibrium in case with two equal chambers
 
Enthalpy  delta H- heat content- more where higher potential energy so if level of chamber 1 higher than 2, get at equilibrium more beans in chamber 2 because they can’t jump back, so H is the level of the floor so higher where it is higher.

4.        Entropy if we change the floor area by expanding chamber 2, less probability of beans getting back to 1 even if they are on the same level, so more chance of finding bean in 2, so equilibrium constant greater than 1. The floor area represents entropy or disorder or randomness or d S

5.        Work    D G    is a measure of capacity to do work. The greater the free energy between the two chambers, the more work can be done. DG is free energy available to do work. If you keep DG negative, by adding beans to chamber 1 and removing from 2, then we have a steady state . If DG  is neg, it is a favorable reaction

6.        1B

7.        1b

8.        2a Tyrosine versus threonine phosphorylation in cell cycle

9.        2a

10.     2b 17-19

11.     17-20

12.     ubiquitination

13.     17-26

14.     17-28

15.     17-29

16.     17-30

17.     17-33

18.     3a 16-54

19.     Different actin functions

20.     Changes by actin binding proteins

21.     3a or 3b Actin binding proteins

22.     3b 16-90

23.     Myosin-actin interaction 9-5

24.     All from Ca++ release, but different intermediate steps.
Calmodulin instead of troponin controls in smooth. Fig 9-6

25.     Regulation of skeletal vs smooth contraction

26.     Contraction, relaxation mechanisms

27.     Assembly-disassembly

28.     3b control move on MT

29.     4a  Figure 9-9.   Excitation-contraction coupling in skeletal muscle. A tetrad of four L-type Ca2+ channels on the T tubules faces a single Ca2+-release channel of the SR, so that each L-type Ca2+ channel interacts with the foot of one of the four subunits of the Ca2+-release channel. Note that half of the Ca2+-release channels lack associations with L-type Ca2+ channels. DHP, dihydropyridine; SR, sarcoplasmic reticulum.

30.     6a

31.     Tyrosine versus threonine phosphorylation in cell cycle

32.     Comparison of:
 a.near-equilibrium working enzymes-needs high concnetration of enzyme;
b. allosteric enzymes;
enzyme works far from equilibrium: not controled by concentration of substrate
c. enzymes controled by phosphorylation; works far from equilibrium

33.     5b     57-9

34.     Transporters and mtiochondria

35.     Fatty acid metabolism

36.     5a or b 45-5 Transporters in hepatocyte

37.     45-6, breakdown of heme

38.     6a Figure 57-3.   Glucose metabolism. After entering a liver or skeletal-muscle cell, glucose is immediately phosphorylated to glucose-6-phosphate, which can have three fates: glycolysis, breakdown via the pentose phosphate shunt, and glycogen synthesis. ATP, adenosine triphosphate; NADPH, nicotinamide adenine dinucleotide phosphate; UDP, uridine diphosphate; UTP, uridine triphosphate.

39.     6b

40.     6b

41.     7aKinds of microtubules in spindle

42.     Process of mitosis

43.     Overlap microtubules

44.     Pacman or disassembly

45.     Tyrosine versus threonine phosphorylation in cell cycle